There are doubles since there are not enough villains in total.

Aries:
Dabi

Taurus:
Overhaul

Hehe. You dead

Gemini:
Shigaraki

Cancer:
Spinner

Leo:
Magne

Virgo:
All For One

you really dead now-

Libra:
Mustard

Scorpio:
Kurogiri

Sagittarius:
Toga

Capricorn:
Mr. Compress

Aquarius:
Dabi

Pisces:
Mustard

Thanks BelladonnaOfCrims again for the help