Bruce Wayne/Batman (headmaster)

Steve Rogers/Captain America (history teacher)

Diana Prince/Wonder Woman (combat teacher)

T'Challa/Black Panther (strategy teacher)

Team GEAR:

Gwen Stacy/Spider-Gwen

Edward Brock/Venom

Anna Marie/Rogue

Richard Grayson/Nightwing

Team BRGD:

Barbara Gordon/Batgirl

Jaime Reyes/Blue Beetle

Garfield Mark Logan/Beast Boy

Daniel Fentom/Danny Phantom

Team WALK:

Rose Wilson/Ravager

Akihiro Howlett/Wolverine II

Laura Kinney/X-23

Kori Anders/Starfire

Team CMQR:

Conner Kent/Superboy

Megan Morse/Miss Martian

Quintella Keli/Teen Lantern

Rock Light/Mega Man

Notes:

BRGD is pronounced as "Brigade"

CMQR is pronounced as "Conquer"

The teams will remain until Season 3 ends

Rock Light is a human who can transform into Mega Man thanks to an armor built by his father Thomas Light.